No. Don’t be fooled, most storm doors are made of hollow aluminum tube. Inserting Styrofoam into the aluminum tube does not increase the insulating properties of aluminum storm doors. If you were to measure the temperature of the outside face of a foam filled storm door and compare it to the temperature of the inside face, you would find little or more likely no difference. This is due to the cold being conducted from the outside of the tube to the inside.
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